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#92 - New Study Shows Incinerator Ash More Dangerous Than We Realized, 28-Aug-1988

A new study by a team of engineers at Rutgers, the state university of
New Jersey, shows that municipal incinerator ash is more dangerous than
previously realized.

When household garbage burns, the resulting ash has two parts: fly ash,
most of which is captured from the smoke stack by an air pollution
control system, and the heavier "bottom ash" which falls through the
grate of the combustion chamber into an ash pit; both types of ash must
be carted away. Both types of ash contain toxic heavy metals (chromium,
cadmium, lead, arsenic, zinc, and other metals) as well as organic
compounds (PCBs, dioxins, benzene, and other cancer-causing organics).
Here we will discuss only the metals.

When the ash is thrown away, the metals in the ash become available to
the environment. Currently, such ash is typically heaped on the ground
somewhere, or is dumped in a municipal landfill. Then rainwater seeps
into the ash and begins to dissolve the metals and carry them into the
general environment.

Chemical engineers at Rutgers have released a new study showing that
toxic metals in municipal incinerator ash are more abundant and more
soluble, and therefore more dangerous, than previously thought.

The Rutgers team took samples of household solid waste from three
locales (Pennsauken, NJ, Magnolia, NJ, and Somerset County, NJ) and
burned them in a small (50 ton per day) solid waste incinerator. They
captured the fly ash and the bottom ash. The solid waste samples did
not include substantial quantities of industrial trash but were
restricted to household wastes.

The actual composition of the ash is shown in Table 1. There were, of
course, other elements and compounds in the ash, but the Rutgers team
did not measure these because they are not regulated under federal law.
As is obvious from these numbers (which are all given as parts per
million, or ppm) there are large quantities of metals in the ash.

Table 2 shows how many pounds of metal are found in each ton of ash,
using the "average" values given at the bottom of Table 1. (We, not the
Rutgers group, did the averaging in Table 1.)

The numbers are quite astonishing. Take lead, for example. If a 2000
ton-per day incinerator produces 500 tons of ash per day, and if 10% is
fly ash and 90% is bottom ash, the total daily ash will contain 2935
pounds of lead. That's a ton and a half of lead per day. The same
arithmetic tells us that one day's ash will contain 48 pounds of
chromium, 61 pounds of cadmium, and 97 pounds of arsenic. In a year's
time (operating 5 days a week, 52 weeks a year), such an incinerator
will put out 12,610 pounds of chromium, 15,990 pounds of cadmium,
25,246 pounds of arsenic, and three quarters of a million pounds of
lead (763,256, actually). These are all metals that are toxic in
microgram quantities (there are 454 million micrograms in one pound).

ALL of this metal will most likely leach into the environment sooner or
later. But the law does not view it that way. The law requires that the
ash be tested for toxicity using something called the "extraction
procedure" toxicity test (EP Tox Test for short). The EP tox test
asks, "If we mix the ash with a dilute solution of acetic acid and then
test the dilute solution, how much metal do we find has dissolved into
the solution?" If we find more than 100 times as much metal as is
allowed in drinking water, then the ash is declared a "hazardous
waste." If the metals are not present at levels 100 times the drinking
water standard, the ash is declared "nonhazardous" no matter how many
tons of dangerous metals it may contain. (This system clearly does not
protect the public, but it's what the EPA [U.S. Environmental
Protection Agency] has set, so it's what we've got.)

Many scientists have criticized the EP Tox Test for a variety of
reasons. So the EPA has proposed a new test, which will soon replace
the EP Tox test. The new one is called the TCLP extraction test (short
for Toxicity Characteristic Leaching Procedure). The details of the
TCLP are different from the EP Tox test, but the basic idea is the same.

The Rutgers team tested the ash from the three locales with the EP Tox
Test, and the Pennsauken sample was given the TCLP test. All the fly
ash samples were deemed "hazardous" for both lead and cadmium by the EP
Tox test. The TCLP results showed that THE TCLP LEACHED EVEN MORE
METALS THAN THE EP TOX TEST.

Lessons from the work at Rutgers: (1) The amount of metal in solid
waste ash varies from place to place with socio-economic status,
geographic location, season, collection patterns, and recycling
practices. Your local waste stream should be sampled every 2 weeks for
a year to see what it really contains; some consulting
firm's "estimate" of what's in your local waste is most likely off; (2)
the quantity of toxic metals in your waste may be very high and the
toxicity will endure forever; ask how long the landfill liners are
guaranteed. (3) The EP tox test may show that the ash is
legally "hazardous" but the TCLP test is even more likely to show that
the ash is legally hazardous.

Get T.L. Clapp and others, "Municipal Solid Waste Composition and the
Behavior of Metals in Incinerator Ashes," ENVIRONMENTAL PROGRESS, Vol.
7 (Feb., 1988), pgs. 22-30. Dr. Clapp 's address is: Department of
Chemical and Biochemical Engineering, College of Engineering, Rutgers,
P.O. 909, Piscataway, NJ 08854; phone (201) 932-3047 or 932-2213.

TABLE 1-- Metals in ash resulting from combustion of household wastes
(in parts per million)


align=right>490 height=17 > align=right>6970 align=right>4700 height=17>
align=right>50 height=17 > align=right>5 align=right>80 height=17>Somerset height=17>
align=right>52 height=17 > align=right>8 align=right>87 height=17 >Average height=17 >
align=right>44 height=17 >
align=right>282 height=17 >
align=right>3940 height=17 >
align=right>71
valign="bottom">Waste Source ="bottom">Metal Fly
Ash (ppm)
Bottom Ash
(ppm)
Pennsauken
Chromium 30 40
Cadmium 100
Lead 4990
Arsenic 47 118
Zinc 4400
Magnolia
Chromium 73
Cadmium 130
Lead 2838 650
Arsenic 71
Chromium 35
Cadmium 227
Lead 3993 852
Arsenic 112
Chromium 49
Cadmium 37
Lead 2824
Arsenic 100

--Peter Montague

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Descriptor terms: incineration; ash; studies; findings; rutgers
university; ep toxicity; msw; landfilling; heavy metals; cancer;
disease statistics; risk assessment; leachate; groundwater; nj; lead;
chromium; cadmium; arsenic; monitoring; drinking water; hazardous waste
industry; epa; tclp;